Synthesis, characterisation and catalytic use of iron porphyrin amino ester conjugates
نویسندگان
چکیده
منابع مشابه
From porphyrin benzylphosphoramidate conjugates to the catalytic hydrogenation of 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin
Three new porphyrin aminoalkyl dibenzylphosphoramidates were synthesized by nucleophilic aromatic substitution of one p-fluorine atom of 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin (TPPF 20 ) by primary aminoalkyl dibenzylphosphoramidates. The nucleophilic aromatic substitution was promoted by microwave irradiation in N-methyl-2-pyrrolidinone. Attempts to remove the benzyl groups of the pho...
متن کاملPorphyrin and phthalocyanine glycodendritic conjugates: synthesis, photophysical and photochemical properties.
Synthesis of water soluble porphyrin and phthalocyanine derivatives with, respectively, eight and sixteen galactose units has been carried out. The combined preliminary photophysical and photochemical features of the new products suggest that they might be promising photodynamic therapeutic agents.
متن کاملGlycosyl bis-porphyrin conjugates: synthesis and potential application in PDT.
Syntheses of new glycosylated neutral and cationic porphyrin dimers linked at the meso-position via a flexible hydrocarbon chain are described. A detailed 1H and 13C NMR study allows their complete structural elucidation. The UV-visible, fluorescence and MALDI mass spectra are also presented. Photocytotoxicities of these compounds against K562 leukaemia cell line are compared to those of Photof...
متن کاملSynthesis of cationic porphyrin modified amino acids.
Derivatives of amino acids bearing a porphyrin moiety on a side chain were synthesized by coupling a porphyrin to a glutamic acid side chain; the utility of these compounds was demonstrated by their use in solid-phase synthesis of a peptide bearing a cationic porphyrin and by studying its DNA-binding properties.
متن کاملSynthesis, characterisation and catalytic activity of Schiff base Cu(II) metal complex
This study reports the synthesis of chitosan anchored Schiff base, ([2-oxo-1H-indol-3-ylidene] amino) chitosan and its Cu (II) metal complex. The complex was characterized by elemental analysis, FT-IR Spectrum, thermogravimetry analysis .The crystallinity of the compound was analyzed by powder X-ray diffraction technique. The catalytic efficiency of complex was studied in the oxidation of alcoh...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: New Journal of Chemistry
سال: 2017
ISSN: 1144-0546,1369-9261
DOI: 10.1039/c7nj01189j